The calorific value of deisel is less than petrol. I.e. it produces less power when burnt, under similar circumstances to that of petrol. It should logically mean that petrol engines should be more efficient. However that is not the case becuase: -
Deisel engines use the direct injection technique (deisel can catch fire more easily than petrol). In this technique the chances of deisel particles going waste (unburnt) are less.
Petrol engines, on the other hand, need an external spark to ignite and continue burning while the piston is pushed backwards. This results in incomplete burning of petrol molecules. Also, not all the power that is genrated while burning could be tapped. As a result, while petrol engines remain more powerful (due to higher calorific value), they are not as efficient.
Benoy is right that when we will have direct injection in petrol engines then their efficiency will increase manyfolds. They should easily surpass the deisel engines in this department. Another big advatage would be a further increase in power output of petrol engines, coupled with cleaner emissions.
All leading players (worldwide) now have these CRDI (Common rail direct injection) version of petrol engines, though they are not yet deployed in mass market cars yet. However, very soon these will become the norm in cars worlwide.
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