If your car will allow it the best is to turn on AC and heat at the same time while using the defogger setting. Using the AC dehumidifies the air, then the heater makes it hot and increases its ability to absorb moisture. Bye-bye annoying fog.
Not all cars can do this, but for those that will the setting is usually temperature to warm or hot, AC button on (if present), and the mode setting to defog. Some cars without a separate AC button will activate the AC automatically in defog mode, while those with an AC button generally require that it be set to on if they support this. The defog setting is also important. If the car does support this mode of operation as a general rule it won't use the heater and AC at the same time unless the mode is set to defog.
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